Thermally-stable large strain in Bi(Mn0.5Ti0.5)O3 modified 0.8Bi0.5Na0.5TiO3-0.2Bi0.5K0.5TiO3 ceramics |
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Authors: | Ling Li Ji Zhang Rui-Xue Wang Mupeng Zheng Yudong Hou Haibo Zhang Shan-Tao Zhang Mankang Zhu |
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Affiliation: | 1. National Laboratory of Solid State Microstructures and Department of Materials Science and Engineering, College of Engineering and Applied Science & Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing, 210093, China;2. College of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China;3. School of Materials Science and Engineering, State Key Laboratory of Material Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan, 430074, China |
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Abstract: | (1-x)0.8Bi0.5Na0.5TiO3-0.2Bi0.5K0.5TiO3]-xBi(Mn0.5Ti0.5)O3 (x = 0–0.06, BNKMT100x) lead-free ferroelectric ceramics were prepared via solid state reaction method. Bi(Mn0.5Ti0.5)O3 induces a structure transition from rhombohedral-tetragonal morphotropic phases to pseudo-cubic phase. Moreover, the wide range of compositions within x = 0.03–0.055 exhibit large strain of 0.31%–0.41% and electrostrictive coefficient of 0.027–0.041 m4/C2. Especially, at x = 0.04, the large strain and electrostrictive coefficient are nearly temperature-independent in the range of 25–100 °C. The impedance analysis shows the large strain and electrostrictive coefficient originate from polar nanoregions response due to the addition of Bi(Mn0.5Ti0.5)O3. |
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Keywords: | Corresponding authors Lead-free Electric property Large strain Composition-insensitivity Thermal stability |
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