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Ion reduction in iron oxide and oxyhydroxide nanoparticles during ultrasonic treatment
Authors:SV Stolyar  OA Bayukov  RN Yaroslavtsev  YuV Knyazev  VP Ladygina  YuV Gerasimova  RS Iskhakov
Affiliation:1. Siberian Federal University, Krasnoyarsk, Russia;2. Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia;3. Krasnoyarsk Scientific Center, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Abstract:The effect of ultrasonic treatment of iron oxide and iron oxyhydroxide nanoparticles (ferrihydrite nanoparticles synthesized by Klebsiella oxytoca microorganisms, ferrihydrite nanoparticles synthesized by a chemical method and hematite nanoparticles) is studied. Samples of nanoparticles were investigated using transmission electron microscopy, Mössbauer spectroscopy and X-ray diffraction methods. The formation of the α-Fe metal phase from nanoparticles of iron oxides and iron oxyhydroxides was detected. The metal phase is formed as a result of the reduction of iron ions during cavitation treatment. According to the experimental results, the presence of a protein or a polysaccharide component is necessary for the course of this reaction.
Keywords:Corresponding author    Nanoparticles  Ferrihydrite  Ultrasonic cavitation
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