Si/C/N纳米粉体的吸波特性研究

采用ＸＲＤ研究了氮原子百分含量为１１．６１%的Ｓｉ/Ｃ/Ｎ纳米粉体的相组成,并测定了粉体介电常数根据介电常数,分别优化设计了单层和双层的吸波徐层,设计的吸波涂层对８~１８ＧＨｚ范围的电磁波有较好的吸收作用．设计厚度为２．７ｍｍ的单层吸波涂层,在８~１５ＧＨｚ范围内反射率＜－５ｄＢ设计厚度为２．８ｍｍ的双层吸波涂层,在８~１８ＧＨｚ频率范围内电磁波的反射率均＜－５ｄＢ,反射率＜－８ｄＢ的频带为６ＧＨｚ．针对纳米粉体的吸波特性,提出了Ｓｉ/Ｃ/Ｎ纳米粉体的吸波机理．

Dielectric Properties of Si/C/N Nano Powders

Si/C/N nano powders with 11.61% nitrogen were prepared by CVD. XRD pattern and permittivity of the powders were investigated. On the basis of permittivity of the powders, radar absorber structures of single- and double-layer were designed. A single-layer absorber coating with a reflection coefficient less than -5dB in the frequency range of 8-15GHz was designed with a thickness of 2.7mm. A double-layer radar absorber coating with a reflection coefficient less than -5dB in the frequency range of 8-18GHz was also designed with a thickness of 2.8mm. The range of the reflection coefficient being less than -8dB was 6GHz for the designed double-layer radar absorber. The radar absorbing mechanism of Si/C/N nano powders was also interpreted. The SiC microcrystalline in the nano composite powder dissolves a great deal of nitrogen. The charged defects are caused by N atoms occupying the sites of C in SiC moved in response to the electric field. The dielectric relaxation caused by the charged defects moved in response to the electric field is the main way of the Si/C/N nano powders with absorbing properties.