Dilute solution properties of methyl methacrylate—acrylonitrile copolymer (MA1)

This paper deals with studies on the dilute solution properties of methyl methacrylate—acrylonitrile copolymer of 0.289 mole fraction (mf) of acrylonitrile composition. Mark—Houwink parameters for this copolymer have been evaluated in acetonitrile (MeCN), 2-butanone (MEK), dimethylformamide (DMF) and γ-butyrolactone (γ-BL). The solvent power is found to be in the order of MEK < MeCN < DMF < γ-BL at 30°C. Herein, probably for the first time, the steric factor for the copolymer is found to be lower than that for the parent homopolymers and the excess interaction parameter, χ_AB is found to be negative. This probably suggests that the units are compatible to each other.