| 含异靛单元染料的合成及在DSSC中的研究 |
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| 引用本文： | 王钢,谭海军,刘波,陈旭珠,张怡平,吴莹莹,潘春跃.含异靛单元染料的合成及在DSSC中的研究[J].广州化工,2012,40(14):98-100. |
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| 作者姓名： | 王钢 谭海军 刘波 陈旭珠 张怡平 吴莹莹 潘春跃 |
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| 作者单位： | 中南大学化学化工学院有机高分子所,湖南长沙,410083 |
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| 摘 要： | 我们以三苯胺为电子给体,氰基丙烯酸为电子受体和锚定基团,首次使用窄带隙共轭单元异靛设计合成了一个D-π-A型全有机染料TPAID1,对其进行在染料敏化太阳能电池中的性能进行了一些列的表征,测定了染料在氯仿溶剂中的紫外-可见吸收光谱,并对其进行了DSSC器件表征,在AM 1.5 G,100 mW/cm2下,染料TPAID1的电池能量转换效率为0.59%(Jsc=1.59 mA/cm2,Voc=0.55 V,FF=0.69)。
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| 关 键 词： | 染料敏化太阳能电池 纯有机染料 异靛 共轭单元 |
The Research of A New Dye Synthesis Based on Isoindigo -Conjugate Unit for DSSC |
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| WANG Gang,TAN Hai-jun,LIU Bo,CHEN Xu-zhu,ZHANG Yi-ping,WU Ying-ying,PAN Chun-yue.The Research of A New Dye Synthesis Based on Isoindigo -Conjugate Unit for DSSC[J].GuangZhou Chemical Industry and Technology,2012,40(14):98-100. |
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| Authors: | WANG Gang TAN Hai-jun LIU Bo CHEN Xu-zhu ZHANG Yi-ping WU Ying-ying PAN Chun-yue |
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| Affiliation: | WANG Gang, TAN Hai - jun , LIU Bo , CHEN Xu - zhu , ZHANG Yi -ping, WU Ying - ying , PAN Chun - yue ( College of Chemistry and Chemical Engineering, Central South University, Hunan Changsha 410083, China) |
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| Abstract: | A novel pure organic dye TPAIDI was designed and synthesized, which had a D -~ -A system based on indigo a w - conjugated system, containing a triphenylamine （TPA） electron - donating group and cyanoacrylic acid as an electron acceptor and an anchoring group. The photophysical and electrochemical properties of the dye were investigated by absorption spectrometry and DSSC device characterization. The DSSC based on TPAID1 produced 0.59% of energy conversion efficiency（J50= 1.59 mA/cm2, Voc =0.55 V, FF =0.69） under 100 mW/cm2 simulated AM 1,5 G solar irra- diation. |
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| Keywords: | dye -sensitized solar cells pure organic dye isoindigo conjugated unit |
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