| 磷钒酸盐红色发光粉的制备及性能研究 |
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| 引用本文： | 王绍成,陈珊珊,廖文举,周万丰,王卓.磷钒酸盐红色发光粉的制备及性能研究[J].广州化工,2012,40(10):66-68. |
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| 作者姓名： | 王绍成 陈珊珊 廖文举 周万丰 王卓 |
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| 作者单位： | 烟台大学环境与材料工程学院,山东烟台,264005 |
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| 基金项目： | 山东省烟台大学大学生科技创新资助项目 |
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| 摘 要： | 采用燃烧法合成了一种近紫外激发的Ca3((P,V)O4)2:Eu3+发光材料,用X射线衍射谱、荧光光谱对样品进行了表征。结果表明,荧光粉基质Ca3((P,V)O4)2具有畸变的Ca3(VO4)2的结构,VO34-取代了部分的PO34-,但Ca2+的半径与Eu3+接近,因此Eu3+容易进入晶格,表现出良好的发光性能。荧光光谱分析发现荧光粉可被376 nm紫外光激发,主发射峰值位于620 nm(Eu3+离子的5D0→7F2跃迁)的红光,同时详细研究了Eu3+离子掺杂浓度、引发温度及尿素用量对荧光粉发光性能的影响。
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| 关 键 词： | 磷钒酸盐 红色发光粉 燃烧法 |
Synthesis and Luminescence of Vanadium Phosphate Red Phosphors |
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| WANG Shao-cheng,CHEN Shan-shan,LIAO Wen-ju,ZHOU Wan-feng,WANG Zhuo.Synthesis and Luminescence of Vanadium Phosphate Red Phosphors[J].GuangZhou Chemical Industry and Technology,2012,40(10):66-68. |
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| Authors: | WANG Shao-cheng CHEN Shan-shan LIAO Wen-ju ZHOU Wan-feng WANG Zhuo |
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| Affiliation: | (School of Environmental and Materials Engineering,Yantai University, Shandong Yantai 264005,China) |
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| Abstract: | Ca3（（P,V）O4）2：Eu^3＋ phosphor powder with near ultraviolet excitation was synthesized by combustion method.XRD and photoluminescence were employed to characterize their properties.The results showed that the host Ca3（（P,V）O4）2 was presented as a distorted Ca3（VO4）2 structure.A part of PO3-4 was replaced by VO3-4.Due to the similar ion radius of Ca^2＋ ion and Eu3＋ ion,the powders exhibited the strongest emission intensity.The photoluminescence spectra indicated that the phosphor can be excited by UV light（376 nm）,the main emission peak was at 620 nm（Eu3＋ion of 5D0→7F2 transition） of the red light,and the effect of Eu3＋ doping concentration,initiation temperature and the amount of urea on the phosphor luminescent properties was studied. |
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| Keywords: | vanadium phosphate red light phosphor combustion method |
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