| XPS研究共掺杂TiO2可见光光催化活性 |
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| 引用本文： | 陈淑敏,曹广连,袁志勇,曹广秀. XPS研究共掺杂TiO2可见光光催化活性[J]. 广州化工, 2012, 40(13): 115-117 |
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| 作者姓名： | 陈淑敏 曹广连 袁志勇 曹广秀 |
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| 作者单位： | 1. 商丘师范学院化学化工学院,河南商丘,476000
2. 上海现代哈森（商丘）药业有限公司,河南商丘,476000 |
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| 基金项目： | 河南省基础与前沿技术研究计划项目 |
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| 摘 要： | 利用X-射线光电子能谱(XPS)分析掺杂元素对二氧化钛中O1s和Ti2p的结合能峰的变化。从实验数据求出△(O-Ti)值,分析变化的原因。数据显示:共掺杂后△(O-Ti)的值的变化范围为71.2～71.5 eV之间,掺杂后△(O-Ti)值大于纯TiO2。可见光光催化氧化4-氯苯酚结果表明:随着△(O-Ti)值的增大,可见光光催化活性逐步提高。
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| 关 键 词： | XPS 共掺杂 二氧化钛 结合能 光催化 |
XPS Study on Visible Light Photocatalytic Performances of Codoping TiO2 |
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| CHEN Shu-min,CAO Guang-lian,YUAN Zhi-yong,CAO Guang-xiu. XPS Study on Visible Light Photocatalytic Performances of Codoping TiO2[J]. GuangZhou Chemical Industry and Technology, 2012, 40(13): 115-117 |
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| Authors: | CHEN Shu-min CAO Guang-lian YUAN Zhi-yong CAO Guang-xiu |
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| Affiliation: | CHEN Shu - minI , CAO Guang - lian2, YUAN Zhi - yongI , CAO Guang - xiu1 ( 1 College of Chemistry and Chemical Engineering, Shangqiu Normal University, Henan Shangqiu 476000 ; 2 Shanghai Modem Hasen (Shangqiu) Pharmaceutical Co. , Ltd. , Henan Shangqiu 476000, China) |
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| Abstract: | The changes of binding energies for O1 s and Ti2p in codoping titanium dioxides were analyzed using X - ray photoelectron spectroscopy （XPS）. The binding energy difference A （O -Ti） was calculated by a set of available ex- perimental data on the binding energies of Ti2p3/2 and O1 s core levels and the reasons were summarized. The data presen- ted that the a （O -Ti）was in range of 71.2 -71.5 eV, and was larger than that of pure TiO2. The results showed that the visible light photocatalytic performances were enhanced with enhancing of a （O -Ti）. |
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| Keywords: | XPS codoping Ti02 binding energy photocatalysis |
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