首页 | 本学科首页   官方微博 | 高级检索  
     


Spin Probe Study of IPN-like Systems based on Polyethylene and Polymethacrylates
Authors:Jozef Ti&#x;o  Marta Klimov  Agnesa Fiedlerov  Eberhard Borsig
Abstract:A system similar to an interpenetrating polymer network (IPN), based on polyethylene/poly(methylmethacrylate-co-dodecyl methacrylate), was studied by the spin probe method with a nitroxide spin probe, 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO). The influence of changes in the composition of the copolymer (methyl methacrylate-co-dodecyl methacrylate) on the molecular mobility and composition of the IPNs is characterized by changes of the empirical spectral parameters T50G and τR. The molecular mobility was shown to diminish with rising content of methyl methacrylate in the copolymer. © of SCI.
Keywords:polyethylene  poly(methacrylate)s  IPNs  spin probe TEMPO  molecular mobility  correlation time
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号