The Role of the Support in the Oxidative Destruction of Chlorobenzene on Pt/Zeolite Catalysts: An FT-IR Investigation |
| |
| Authors: | Salvatore Scirè Simona Minicò |
| |
| Affiliation: | (1) Laboratorio di Chimica delle Superfici e Catalisi Industriale, Dipartimento di Ingegneria Chimica e di Processo, Università di Genova, P.le Kennedy, 16129 Genova, Italy;(2) Facultad de Ciencias Químicas, Departamento de Química Inorgánica, P. de la Merced s/n, 37008 Salamanca, Spain |
| |
| Abstract: | The vapor-phase cyclohexane oxidative dehydrogenation has been investigated over several catalysts. A typical catalyst for total oxidation, as Mn2O3, materials applied in the field of oxide hydrogenation reactions, as silica-supported vanadia- and niobia-based catalysts, V-, Fe-, and Ce-phosphates used for partial oxidation reactions and ZSM5 zeolite, protonic and Co exchanged, have been tested. Over almost all the catalysts, benzene is the main product obtained, although cyclohexene is obtained with high selectivity at low conversion on phosphate catalysts. |
| |
| Keywords: | cyclohexane oxidative dehydrogenation vapor phase benzene |
| 本文献已被 SpringerLink 等数据库收录！ |
|
