A study of the sulfidation and regeneration reaction cycles of Zn-Ti-based sorbents with different crystal structures |
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Authors: | Suk Yong Jung Jung Je Park Soo Jea Lee Hee Kwon Jun Soo Chool Lee Jae Chang Kim |
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Affiliation: | (1) Department of Chemical Engineering, Kyungpook National University, Daegu, 702-701, South Korea;(2) Department of Chemical Engineering, Pohang University of Science and Technology, Pohang, Gyeongbuk, 790-784, South Korea;(3) Daegu Gyenongbuk Institute of Science and Technology, Daegu, 704-230, South Korea; |
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Abstract: | The reaction cycles of the sulfidation and regeneration of Zn-Ti-based sorbents prepared by a physical mixing method (ZT-700
and ZT-1000) or co-precipitation method (ZT-cp) were tested in a fixed bed micro-reactor at middle temperature (Sulfidation;
480 °C, regeneration; 580 °C). The ZnS produced during sulfidation from the Zn2TiO4 with a spinel structure (ZT-1000, ZT-cp) was easily regenerated even at 550 °C, while the ZnS produced from the ZnO with
a hexagonal structure (ZT-700) needed a temperature higher than 610 °C. After regeneration, each sorbent was restored to its
original crystal structure. The differences in the regeneration properties and the reaction cycles of the sorbents were related
to the original crystal structures rather than to the physical properties such as pore volume and surface area. To study these
differences further, FT-IR, FT-Raman, XRD and TPR were used, and their results including the reaction cycles of the sulfidation
and regeneration on the Zn-Ti based sorbents with different crystal structures were discussed. |
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