镁合金超疏水环氧复合涂层的制备与性能EI北大核心CSCD

传统的超疏水表面的制备过程比较复杂,机械稳定性差,这严重制约了超疏水表面的实际应用。采用“黏合剂+纳米粒子”的方法,在镁合金表面制备一种无氟、持久稳定的超疏水环氧复合涂层。接触角测试结果表明,复合涂层的接触角最高可达160.2°,且在3.5%(质量分数)NaCl溶液中浸泡30天后,接触角仍然高达103°;EIS结果表明,在5个加速老化循环周期后,复合涂层的|Z|_(0.01 Hz)仍高于10^(9)Ω·cm^(2),展现出优异的耐盐雾性能和耐蚀性能;摩擦磨损实验结果显示,在19.6 N的载荷下机械摩擦8 h后,复合涂层的|Z|_(0.01 Hz)高达1.84×10^(9)Ω·cm^(2)。通过“空气垫”的屏障作用,复合涂层能够为镁合金提供高效且持久的腐蚀防护,“黏合剂+纳米粒子”策略为超疏水涂层的制备提供了新的思路。

Preparation and properties of superhydrophobic epoxy composite coatings on magnesium alloys

The traditional preparation process of superhydrophobic surfaces(SHS) is complicated and the mechanical stability of SHS is less than satisfactory in most cases, which seriously restricts the practical application. The "binder+nanoparticles" strategy was used to prepare a nonfluorinated, durable and stable superhydrophobic epoxy composite coating on magnesium alloy. The contact angle test results show that the maximum contact angle of the composite coating is 160.2°, and the contact angle is still as high as 103° even after 30 days of soaking in 3.5%(mass fraction) NaCl solution; EIS results indicate that the |Z|_{0.01 Hz} of the composite coating is still above 10⁹ Ω·cm² even after five accelerated aging cycles, demonstrating excellent resistance to salt fog and anticorrosion performance; Friction and wear test results reveal that the |Z|_{0.01 Hz} of the composite coating is as high as 1.84×10⁹ Ω·cm² after mechanical friction under 19.6 N load for 8 h. Due to the excellent blocking barrier of "air cushion", the composite coating can provide efficient and durable corrosion protection for magnesium alloy and the "adhesive+nanoparticles" strategy provides a new direction for the preparation of superhydrophobic coating.