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Ti添加对WC-Ni3Al硬质合金微观组织与力学性能的影响
引用本文:吴祖骥,范佳锋,李京懋,朱德智,屈盛官,李小强.Ti添加对WC-Ni3Al硬质合金微观组织与力学性能的影响[J].材料工程,2022,50(12):103-111.
作者姓名:吴祖骥  范佳锋  李京懋  朱德智  屈盛官  李小强
作者单位:华南理工大学 国家金属材料近净成形工程技术研究中心, 广州 510640
基金项目:国家自然科学基金项目(51474108);广东省自然科学基金重点项目(2018B030311051);宜春经开区创新驱动发展科技计划项目(1203)
摘    要:为提高WC-Ni3Al硬质合金的力学性能,采用放电等离子烧结制备Ti掺杂的WC-Ni3Al硬质合金,并研究不同Ti添加量对WC-Ni3Al硬质合金微观组织和力学性能的影响。结果表明: Ti的添加减小WC-Ni3Al块体样品中反应生成的少量Al2O3的尺寸,并且使Al2O3的分布更加均匀。一方面,小尺寸的Al2O3与原位生成的(Ti, W)C协同提高WC-Ni3Al块体样品的硬度;另一方面,适量Ti的添加还提高WC-Ni3Al硬质合金的断裂韧度,这是由于原位生成的(Ti, W)C与WC有较好的界面结合,增加对裂纹扩展的桥接与偏转作用。当添加3%(质量分数)的Ti时,WC-Ni3Al硬质合金获得了优异的力学性能,硬度和断裂韧度分别为(19.29±0.18) GPa和(13.14±0.24) MPa·m1/2

关 键 词:Ti掺杂  WC-Ni3Al  原位生成(Ti    W)C  微观组织  力学性能  
收稿时间:2021-11-30

Effect of titanium addition on microstructure and mechanical properties of WC-Ni3Al cemented carbide
Zuji WU,Jiafeng FAN,Jingmao LI,Dezhi ZHU,Shengguan QU,Xiaoqiang LI.Effect of titanium addition on microstructure and mechanical properties of WC-Ni3Al cemented carbide[J].Journal of Materials Engineering,2022,50(12):103-111.
Authors:Zuji WU  Jiafeng FAN  Jingmao LI  Dezhi ZHU  Shengguan QU  Xiaoqiang LI
Affiliation:National Engineering Research Center of Near-net-shape Forming Technology for Metallic Materials, South China University of Technology, Guangzhou 510640, China
Abstract:Ti-doped WC-Ni3Al cemented carbide was prepared by spark plasma sintering for improving mechanical properties. The effect of different Ti contents on the microstructure and mechanical properties of WC-Ni3Al cemented carbide was investigated. The results show that due to Ti addition, the small amount of Al2O3reactively formed in WC-Ni3Al is smaller and more uniform than the sintered sample without adding Ti. The refinement of Al2O3 and the in-situ (Ti, W) C synergistically enhance the hardness of the WC-Ni3Al cemented carbide. Meanwhile, the fracture toughness is improved because the in-situ (Ti, W)C and WC have a better interface combination, facilitating the bridging and deflection formation of cracks. The WC-Ni3Al cemented carbide with 3% (mass fraction) Ti obtains the optimal mechanical properties, with hardness of (19.29±0.18) GPa and fracture toughness of (13.14±0.24) MPa·m1/2.
Keywords:Ti-doped  WC-Ni3Al  in-situ (Ti  W)C  microstructure  mechanical property  
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