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Crystallization process of zeolite ZSM-5 and zeolite ZSM-35 in a special autoclave
Affiliation:1. Central Geophysical Expedition JSC, Moscow, Russia;2. Institute of Petroleum Geology and Geophysics SB RAS, Novosibirsk, Russia;3. Novosibirsk State University, Novosibirsk, Russia;4. Sobolev Institute of Mathematics SB RAS, Novosibirsk, Russia
Abstract:By use of a special autoclave, the crystallization process of the dehydrated amorphous gels was studied in the Na2Osingle bondAl2O3single bondSiO2 ethylenediamine (EDA) — triethylamine (Et3N) — H2O system. In one run, zeolites ZSM-5 and ZSM-35 can be simultaneously synthesized at different areas of the autoclave. The data demonstrate that Gabelica's hypothesis (Gabelica, Z., Blom, N. and Derouane, E.G.Appl. Catal. 1983,5, 227) could be correct at some conditions.
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