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Porous rod-shaped Co3O4 derived from Co-MOF-74 as high-performance anode materials for lithium ion batteries
Affiliation:1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, Jiangsu, China;2. Jiangsu Key Laboratory of Advanced Metallic Materials, Nanjing 211189, Jiangsu, China;1. National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia;2. University of Nova Gorica, Vipavska 13, 5000 Nova Gorica, Slovenia;3. University of Ljubljana, Vecna pot 113, 1000 Ljubljana, Slovenia
Abstract:Porous rod-shaped Co3O4 has been successfully synthesized by one-step thermal annealing of the as-prepared Co-MOF-74 precursor and tested as anode materials for lithium ion batteries. The porous rod-shaped Co3O4 is found to be very attractive for lithium-ion batteries. It demonstrates a reversible capacity of 683 mAh/g after 80 cycles at 100 mA/g and an excellent rate performance with high average discharge specific capacities of 1231, 1026, 733 and 502 mAh/g at 50, 100, 200 and 400 mA/g, respectively. The excellent electrochemical performance should be due to the porous structural and composition characteristics.
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