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The electro-optic performance and photovoltaic effect of organic devices based on cesium carbonate/Al/molybdenum trioxide intermediate connector
Affiliation:1. College of Physics and Electronics Engineering, Hengyang Normal University, Hengyang 421008, China;2. Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou 215123, China;3. Department of Materials Science and Engineering, Monash University, Clayton, Victoria 3800, Australia;1. Thin Film Nano & Microelectronics Research Laboratory, Artie McFerrin Department of Chemical Engineering, Texas A&M University, College Station, TX 77843-3122, USA;2. Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P.R. China;1. Department of Chemical Engineering, University of Rochester, Rochester, NY 14627, USA;2. Department of Chemistry, D''Youville College, Buffalo, NY 14201, USA;3. Institute for Advanced Study, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China;1. Department of Creative Convergence Engineering, Hanbat National University, Daejon 34158, Republic of Korea;2. Department of Display Engineering, Pukyong National University, Busan 48513, Republic of Korea;1. State Key Laboratory on Integrated Optoelectronics, College of Electronics Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, People’s Republic of China;2. Department of Mechanical and Electronic Engineering, Liaoning Provincial College of Communications, 102 Shenbei Road, Shenbei New District, Shenyang 110122, People’s Republic of China;1. School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China;2. Key Laboratory of Display Materials and Photoelectric Devices, Ministry of Education, Tianjin 300384, China;3. Tianjin Key Laboratory of Photoelectric Materials and Devices, Tianjin 300384, China;4. College of Science, Tianjin University of Technology, Tianjin 300384, China
Abstract:An intermediate connector of Cs2CO3/Al/MoO3 used in tandem organic light-emitting diodes (OLEDs) was investigated in this work. Here, an ultrathin Cs2CO3/Al was used as an electron-injection layer (EIL) from MoO3 to the adjacent electron transporting layer (ETL). To verify the function of this intermediate connector, the device performances were evaluated through current density-voltage-luminance characteristics, current density-efficiency curves, and EL spectra. Additionally, the effect of photon energy on carriers behavior in the Cs2CO3/Al/MoO3 connector is also estimated. The electrical properties and EL spectra of tandem OLEDs show that the Cs2CO3/Al/MoO3 can function well for charge generation and transport, and the current density-voltage curves of Cs2CO3/Al/MoO3 based special multilayer device shows the photovoltaic effect as a photovoltaic cell.
Keywords:Intermediate connectors  Organic light-emitting diodes  Tandem OLED  Photovoltaic effect
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