Manganese(III) mediated synthesis of A2B Mn(III) corroles: A new general and green synthetic approach and characterization |
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| Affiliation: | 1. Institute of Chemistry, Eötvös Loránd University, Pázmány Péter sétány 1/A, 1117 Budapest, Hungary;2. Sanofi R&D Chilly Mazarin, France;1. Department of Chemistry, South China University of Technology, Guangzhou, Guangdong 510640, China;2. State Key Laboratory of Optoelectronics Materials and Technologies, Sun-Yat Sen University, Guangzhou 510275, China;1. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, PR China;2. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, PR China;3. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210000, PR China;4. Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037, PR China;1. Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan;2. National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan |
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| Abstract: | A new general and green synthetic protocol for the synthesis of manganese(III) metallocorroles has been developed from substituted aryl aldehydes and 5-(4-nitrophenyl)dipyrromethane using manganese salt as template. This is the first report in the synthesis of corroles: the formation of direct C C bond through metal initiation. This method allows higher working concentrations than those previously reported. The new A2B manganese(III) metallocorroles were synthesized in good yield for different applications. The single crystal X-ray structure of 10-(3,4,5-fluorophenyl)-5,15-bis(4-nitrophenyl)manganese(III) corrole is also reported and shows that manganese atom is situating atop on macrocyclic plane. |
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