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Preparation and properties of electrically conductive,flexible and transparent silver nanowire/poly (lactic acid) nanocomposites
Affiliation:1. Department of Physics, Microelectronics and Instrumentation Laboratory, Av de l’environnement, 5019 Monastir, Tunisia;2. CNRS, Centrale Lille, ISEN, Univ. Valenciennes, UMR 8520-IEMN, Univ. Lille, 59000, Lille, France;1. State Key Laboratory of Polymer Physics and Chemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China;2. University of Chinese Academy of Sciences, Beijing 100049, PR China;1. Department of Chemical Engineering, McMaster University, Hamilton, Ontario, L8S 4L7, Canada;2. Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario, L5K 2L1, Canada;3. Department of Chemistry and Chemical Biology, MAX Diffraction Facility, McMaster University, Hamilton, Ontario, L8S 4L8, Canada;1. Graduate School of Environmental Studies, Tohoku University, 6-6-20, Aramaki, Aoba-ku, Sendai 980-8579, Japan;2. Department of Material Science, University of Shiga Prefecture, 2500 Hassaka-cho, Hikone City, Japan;1. Department of Chemistry, College of Science, Shanghai University, 99 Shangda Road, Shanghai, 200444, PR China;2. Center for Supramolecular Chemistry and Catalysis, Shanghai University, 99 Shangda Road, Shanghai, 200444, PR China;3. Printable Electronics Research Center, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences, 398 Ruo Shui Road, SEID SIP, Suzhou, 215123, PR China;4. Department of Physics and Astronomy, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, PR China
Abstract:As the everyday use of petroleum-based products has raised environmental concerns, there is an urgent need to replace them with green materials. In this work, an eco-friendly, highly conductive, flexible silver nanowire/poly (lactic acid) film has been fabricated through a simple casting method by embedding the silver nanowires (AgNWs) below the surface of the poly lactic acid (PLA) matrix. The fabricated film has a high optical transparency of 89.5% with a sheet resistance of 64.8 Ω/□ and a figure of merit (FoM) of 4.92 × 10−3 Ω−1 which is comparable to that of indium tin oxide (ITO). These films demonstrate excellent flexibility, great adhesion, smooth surface with root mean square (RMS) roughness of 11.7 nm and high mechanical properties with tensile strength and Young's modulus of 39.8 (MPa) and 1.6 (GPa). The results obtained from different testing methods show that the AgNW/PLA nanocomposites are potential candidates in flexible electronics and optoelectronics.
Keywords:Poly lactic acid  Silver nanowire  Nanocomposite  Electrically conductive  Eco-friendly
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