| 浆态床法合成二甲醚的模拟研究 |
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| 引用本文： | 洪若瑜,庄银枪,杨伟. 浆态床法合成二甲醚的模拟研究[J]. 计算机与应用化学, 2004, 21(6): 817-822 |
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| 作者姓名： | 洪若瑜 庄银枪 杨伟 |
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| 作者单位： | 苏州大学化学化工学院江苏省有机合成重点实验室,江苏,苏州,215006;中国科学院过程工程研究所多相反应开放实验室,北京,100080;苏州大学化学化工学院江苏省有机合成重点实验室,江苏,苏州,215006 |
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| 基金项目： | 中国科学院"百人计划" |
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| 摘 要： | 对于直接以合成气作为原料，使用Cu-Zn-Al和γ-Al2O3构成的双重催化剂、采用浆态床法合成二甲醚的反应体系，使用全混流反应器模型结合化学反应动力学进行模拟。组分方程使用超松弛迭代方法并结合C 编程进行求解，编制了计算机程序。通过模拟计算，讨论了压力、温度、空速、催化剂配比、反应气中不同氢碳比以及CO2含量对反应收率、DME选择性的影响，并讨论了在不同氢碳比下对CO转化率和CO与H2总转化率的影响，从而寻找合适的反应条件，为工业化生产提供参考。
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| 关 键 词： | 浆态床 二甲醚 模拟 |
Numerical modeling and simulation on dimethyl ether synthesis in a bubble column slurry reactor |
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| HONG RuoYu,ZHUANG YinQiang,YANG Wei. Numerical modeling and simulation on dimethyl ether synthesis in a bubble column slurry reactor[J]. Computers and Applied Chemistry, 2004, 21(6): 817-822 |
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| Authors: | HONG RuoYu ZHUANG YinQiang YANG Wei |
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| Affiliation: | HONG RuoYu~ |
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| Abstract: | A complete-mixing-flow-reactor model together with detailed chemical reaction kinetics was used to simulate the synthesis ofdimethyl ether(DME)in a bubble column slurry reactor using syngas directly.The derived non-linear equations were solved using un-der-relaxation iteration method.The programming language C++ was employed to implement the numerical algorithm.The influencesof pressure,temperature and superficial gas velocity in the reactor,catalyst ratio,CO/H_2 ratio and CO_2 content of the feed gas on theconversion,yield and DME selectivity were studied.The influences of different CO/H_2 ratio on CO conversion and total conversionwere also studied.The optimal reaction conditions were found,which can be used as a worthwhile reference for engineering scale-upand design. |
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| Keywords: | slurry reactor dimethyl ether modeling simulation |
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