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黑曲霉两步法与化学氧化联合浸出花岗岩铀矿石
引用本文:祖媛媛,李广悦,孙静,李芳艳,王永东.黑曲霉两步法与化学氧化联合浸出花岗岩铀矿石[J].核化学与放射化学,2021,43(2):142-147.
作者姓名:祖媛媛  李广悦  孙静  李芳艳  王永东
作者单位:南华大学 铀矿冶生物技术国防重点学科实验室,湖南 衡阳421001;南华大学 极贫铀资源绿色开发技术湖南省重点实验室,湖南 衡阳421001
基金项目:国家自然科学基金资助项目(51674146)。
摘    要:为了高效浸出花岗岩型铀矿石中的铀,采用黑曲霉两步法和化学氧化联合浸出,研究预培养时间、浸出时间和不同氧化剂及其用量对浸铀效果的影响。结果表明:黑曲霉两步法浸出时,采用预培养36 h的黑曲霉浸铀,浸出时间为72 h时,铀浸出率最高,为59.34%,随着预培养时间和浸出时间的延长,铀浸出率显著下降。加入MnO2、NaClO3和H2O2三种氧化剂对铀浸出率均有不同程度的提高,其中加入2.5%(与矿石质量比)的MnO2时,浸铀效果最佳,铀浸出率最高可达74.09%,与未加氧化剂相比,铀浸出率提高了14.8%。

关 键 词:花岗岩型铀矿  黑曲霉  两步法  氧化剂  联合浸出  

Two-Step Process of Aspergillus Niger-Chemical Oxidation Joint Leaching of Granite Uranium Ore
ZU Yuan-yuan,LI Guang-yue,SUN Jing,LI Fang-yan,WANG Yong-dong.Two-Step Process of Aspergillus Niger-Chemical Oxidation Joint Leaching of Granite Uranium Ore[J].Journal of Nuclear and Radiochemistry,2021,43(2):142-147.
Authors:ZU Yuan-yuan  LI Guang-yue  SUN Jing  LI Fang-yan  WANG Yong-dong
Affiliation:Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy, University of South China, Hengyang 421001, China;Hunan Province Key Laboratory of Green Development Technology for Extremely Low Grade Uranium Resources, Hengyang 421001, China
Abstract:To high-efficiently recover uranium from granite-type uranium ore,a two-step process by Aspergillus niger coupling with chemical oxidants was applied to investigate the effects of pre-culture time,leaching time,oxidant type and dosage on uranium extraction.The results show that the highest uranium recovery of 59.34%is achieved in 36 hours of pre-culture and 72 hours of leaching time in the two-step process by Aspergillus niger.The uranium recovery decreases significantly with the increase of pre-culture time and leaching time.Addition of each of MnO 2,NaClO3 and H2O2 results in an increase in uranium recovery.At a dosage of 2.5%MnO 2 by weight of uranium ore,the highest uranium recovery reaches to 74.09%,having an increase of 14.8%compared with the absence of the oxidant.
Keywords:granite-type uranium ore  Aspergillus niger  two-step method  oxidants  joint leaching
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