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纳米TiO2的改性及其在丙烯酸涂料中的应用
引用本文:陈云华,林安,甘复兴.纳米TiO2的改性及其在丙烯酸涂料中的应用[J].腐蚀科学与防护技术,2007,19(1):58-60.
作者姓名:陈云华  林安  甘复兴
作者单位:1. 武汉大学,资源与环境科学学院,武汉,430079
2. 武汉大学,资源与环境科学学院,武汉,430079;金属腐蚀与防护国家重点实验室,沈阳,110016
摘    要:设计了一种改性纳米TiO2方法,先用带双键官能团的硅烷偶联剂WD70和纳米TiO2反应后,在颗粒表面引入可聚合官能团,然后和甲基丙烯酸甲酯、丙烯酸丁酯共聚合使纳米TiO2颗粒改性.研究结果表明,改性提高了纳米颗粒在涂料中的分散程度,降低了涂层的吸水性和透气性.

关 键 词:纳米TiO2  改性  丙烯酸涂料  吸水
文章编号:1002-6495(2007)01-0058-03
收稿时间:2005-09-17
修稿时间:2006-01-10

MODIFICATION OF NANO-TiO2 AND ITS APPLICATION IN POLYACRYLATE COATING
CHEN Yun-hua,LIN An,GAN Fu-xing.MODIFICATION OF NANO-TiO2 AND ITS APPLICATION IN POLYACRYLATE COATING[J].Corrosion Science and Protection Technology,2007,19(1):58-60.
Authors:CHEN Yun-hua  LIN An  GAN Fu-xing
Affiliation:1. College of Resource and Environmental Science of Wuhan University, Wuhan 430072 ; 2. State Key Laboratory for Corrosion and Protection,Shenyang 110016
Abstract:A method is designed to modify nano-TiO2 particles, by which nanoparticles are modified by silane coupling agent WD-70 with double bond group and then the silane coupling agent copolymerizes with methyl methacrylate and butyl acrylate to produce a thin polymer shell on the nanoparticles. The modified nanoparticles are applied as pigment to polyacrylate coating. The modification of nano-TiO2 can improve its dispersibility in the coating and thereby reduce water absorption and permeability of the polyacrylate coating.
Keywords:nano-TiO2  modification  polyacrylate coating  water absorption  permeability
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