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Effects of Host Doping on Spectral and Long-Lasting Properties of Sm^3+ -Doped Y2O2S
引用本文:姚康 王明文 刘世香 张栌丹 李文军. Effects of Host Doping on Spectral and Long-Lasting Properties of Sm^3+ -Doped Y2O2S[J]. 中国稀土学报(英文版), 2006, 24(5): 524-528. DOI: 10.1016/S1002-0721(06)60156-7
作者姓名:姚康 王明文 刘世香 张栌丹 李文军
作者单位:Department of Applied Chemistry, College of Science and Applied Science, University of Science and Technology Beijing, Beijing 100083, China
基金项目:Project supported by the Foundation of USTB, China.
摘    要:Gd- or Lu-doped long afterglow red phosphor Y2O2S:Sm^3+ was synthesized using the high temperature flux fusion method. The obtained phosphors were analyzed using X-ray diffraction to determine the crystal structure, and the phase analyses show that the product is in single phase. The luminescence spectra and decay curve were measured on a Hitachi F-4500 fluorescence spectrophotometer. The decay time was determined on an ST-900PM weak light photometer. The analyses show that host doping of Lu improves both luminescence and decay time of the materials. The concentration of doped Lu and Sm was varied in order to determine the optimal condition and to synthesize the product with the best properties. The mechanism of the long afterglow was also briefly discussed.

关 键 词:钇氧硫化物 长耐久性能 主体掺杂 稀土元素 光谱性质
文章编号:1002-0721(2006)05-0524-05
收稿时间:2005-12-10
修稿时间:2006-02-20

Effects of Host Doping on Spectral and Long-Lasting Properties of Sm-Doped Y2O2S
Kang , Mingwen Wang, Shixiang Liu, Ludan Zhang,Wenjun Li. Effects of Host Doping on Spectral and Long-Lasting Properties of Sm-Doped Y2O2S[J]. Journal of Rare Earths, 2006, 24(5): 524-528. DOI: 10.1016/S1002-0721(06)60156-7
Authors:Kang    Mingwen Wang   Shixiang Liu   Ludan Zhang  Wenjun Li
Affiliation:aDepartment of Applied Chemistry, College of Science and Applied Science, University of Science and Technology Beijing, Beijing 100083, China
Abstract:Gd- or Lu-doped long afterglow red phosphor Y2O2S:Sm3 was synthesized using the high temperature flux fusion method. The obtained phosphors were analyzed using X-ray diffraction to determine the crystal structure, and the phase analyses show that the product is in single phase. The luminescence spectra and decay curve were measured on a Hitachi F-4500 fluorescence spectrophotometer. The decay time was determined on an ST-900PM weak light photometer.The analyses show that host doping of Lu improves both luminescence and decay time of the materials. The concentration of doped Lu and Sm was varied in order to determine the optimal condition and to synthesize the product with the best properties. The mechanism of the long afterglow was also briefly discussed.
Keywords:yttrium oxysulfide  long-lasting properties  host doping  rare earths
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