Thermophysical properties of quinoline as a function of temperature (303–503 K) and pressure (0.1–400 MPa) |
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Authors: | S. L. Randzio D. J. Eatough E. A. Lewis L. D. Hansen |
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Affiliation: | (1) Institute of Physical Chemistry, Polish Academy of Sciences, ul. Kasprzaka 4452, 01-224 Warsaw, Poland;(2) Department of Chemistry, Brigham Young University, 84603 Provo, Utah, USA |
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Abstract: | Measured and derived thermophysical properties of quinoline are reported for pressures up to 400 MPa at temperatures from 303 to 503 K. The specific volume at 353 K was determined from the specific volume at atmospheric pressure measured b) pycnometry and from isothermal compressibilities measured as a function of pressure up to 400 M Pa. Specific volumes, isothermal compressibilities, thermal coellicients of pressure, and isobaric and isochoric heat capacities at pressures up to 4011 MPa are derived at several temperatures. The effects of pressure on the isobaric heat capacity of quinoline, a weakly self-associated liquid. are discussed and compared with the pressure effects on heat capacities ofn-hexane andm-cresol. |
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Keywords: | heat capacity isobaric thermal expansivity isothermal compressibility pressure-scanning calorimetry quinoline specific volume thermal coellicient of pressure |
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