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响应曲面法分析零价铁对普施安蓝H-5R脱色的影响因素
引用本文:张杨,方茜,李文卫,曾建雄.响应曲面法分析零价铁对普施安蓝H-5R脱色的影响因素[J].净水技术,2013,32(4):39-44.
作者姓名:张杨  方茜  李文卫  曾建雄
作者单位:1. 广州大学珠江三角洲水质安全与保护教育重点实验室,广东广州,510006
2. 中国科学技术大学化学系,安徽合肥,230026
基金项目:国家自然科学基金,中央高校基本业务费专项基金
摘    要:该文分别从零价铁(zVI)投加量、粒径、pH值、盐浓度、摇床摇速对偶氮染料普施安蓝H-5R进行脱色速率研究,并通过响应曲面进行试验优化。结果表明在初始染料溶液浓度为200mg/L时,最适投加量为1.5g/L,脱色速率随着粒径和摇床摇速增大而升高,中性和偏酸条件下pH影响不大,高浓度盐可以增加染料的脱色。响应曲面法(RSM)结果还表明不同影响因素之间存在相互作用,从而影响染料脱色。

关 键 词:零价铁(ZVI)  普施安蓝H-5R  脱色效率  响应曲面法(RSM)  影响因素

Influence Factors of Procion Blue H-5R Decolorization by Zero-Valent Iron with Response Surface Methodology
Zhang Yang , Fang Qian , Li Wenwei , Zeng Jianxiong.Influence Factors of Procion Blue H-5R Decolorization by Zero-Valent Iron with Response Surface Methodology[J].Water Purifcation Technology,2013,32(4):39-44.
Authors:Zhang Yang  Fang Qian  Li Wenwei  Zeng Jianxiong
Affiliation:1.College of Civil Engineering, Guangzhou University, Guangzhou 510006, China; 2. Department of Chemistry, University of Scienee and Technology of China, Hefei 230026, China)
Abstract:In this study, zero-valent iron (ZVI) was used to decolorize an azo dye, procion blue H-5R. Effects of ZVI dosage, ZVI particle size, initial pH, salt concentration and shaking speed on decolorization rate were investigated with response surface methodol- ogy. The results indicate that when dye concentration is 200 mg/L and ZVI dosage is 1.5 g/L, decolorization efficiency increases with ZVI particle size and the shaking speed, pH has little effect in neutral or weak acidic environment, and high salt concentration can enhance removal efficiency of dye. The response surface methodology results also demonstrate that the different factors have interac- tive effects on decolorization.
Keywords:zero-valent iron (ZVI)  procion blue H-5R  decolorizaton efficiency  response surface methodology(RSM)  influence factor
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