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内插TOC系数法测定水体中COD研究
引用本文:刘云,邱晓国.内插TOC系数法测定水体中COD研究[J].山东大学学报(工学版),2007,37(4):108-117.
作者姓名:刘云  邱晓国
作者单位:山东省环境监测中心站,山东,济南,250013
基金项目:山东省环境保护科技项目
摘    要:运用废水样品“归一化”处理理念,基本解决了废水TOC测定中悬浮物、共存离子(硫酸根、硝酸根、磷酸根、氯离子、硫离子等)、高含量无机碳(IC)、高碱高盐等因素的干扰,实现了废水TOC的正常测定.运用测定区间“限定化” 理念研究了全省造纸、酿酒、印染、农药、制药、淀粉、味精、橡胶、化工、焦化、电厂等主要行业废水,以及污水处理厂废水和地表水、饮用水等水体TOC与CODCr相关关系.在“归一化”和“限定化”条件下,TOC与CODCr具有良好的相关关系,由此提出了“内插TOC系数法”这一新的COD测定方法.

关 键 词:系数法  总有机碳  化学需氧量  相关性  测定
文章编号:1672-3961(2007)04-0108-10
收稿时间:2007-05-10
修稿时间:2007年5月10日

COD determination by interpolation of the  TOC coefficient method
LIU Yun,QIU Xiao-guo.COD determination by interpolation of the  TOC coefficient method[J].Journal of Shandong University of Technology,2007,37(4):108-117.
Authors:LIU Yun  QIU Xiao-guo
Affiliation:Shandong Provincial Environmental Monitoring Centre,Jinan 250013,China
Abstract:The interference in TOC determination of wastewater was basically solved by use of the conception of normalization method in sample treatment, such as suspended solids,coexistence ions(sulfate,nitrate,phosphate,chloride,sulfur,etc.),high levels of inorganic carbon(IC),high alkali and high-salt.The determination of TOC in wastewater is normalized.Also the correlation between TOC and CODCr in water in Shandong Province was studied.For example,the wastewater of paper making,breweries,dyeing,pesticides,pharmaceuticals,starch,MSG,rubber,chemicals,coke,power plant,sewage treatment plant and surface water,and drinking water.It proves that TOC has a very good correlation with CODCr under the condition of normalization and restricted determination zone. It also founds a new method of COD determination by interpolation of the TOC coefficient method.
Keywords:coefficient method  TOC  CODCr  correlation  determination
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