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纳米NiO作催化剂的扣式锂-氧电池的性能
引用本文:李学良,郭丽彬.纳米NiO作催化剂的扣式锂-氧电池的性能[J].电池,2010,40(5).
作者姓名:李学良  郭丽彬
作者单位:合肥工业大学化工学院,安徽,合肥,230009;可控化学与材料化工安徽省重点实验室,安徽,合肥,230009;合肥工业大学化工学院,安徽,合肥,230009
摘    要:将催化剂纳米NiO掺入多孔炭基氧气电极中,组装成CR2032型锂-氧扣式实验电池,并进行恒流充放电和交流阻抗测试。催化剂纳米NiO可改善电池的电化学性能。在0.1 mA/cm2的电流密度下,电池的首次放电比容量为1 258.4mAh/g,放电电压平台稳定在2.7 V左右,充电电压平台为4.2 V。

关 键 词:纳米氧化镍(NiO)  催化剂  过氧化锂(Li2O2)  锂-氧电池

The performance of Li-oxygen button cell using nano-NiO as catalyst
LI Xue-liang,GUO Li-bin.The performance of Li-oxygen button cell using nano-NiO as catalyst[J].Battery Bimonthly,2010,40(5).
Authors:LI Xue-liang  GUO Li-bin
Affiliation:LI Xue-liang1,2,GUO Li-bin1(1.School of Chemical Engineering,Hefei University of Technology,Hefei,Anhui 230009,China,2.Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering,China)
Abstract:Catalyst nano-NiO was doped into porous carbon based oxygen electrode to assemble CR2032 type Li-oxygen button experimental cell,then galvanostatic charge-discharge and AC impedance tests were taken.Catalyst nano-NiO could improve the electrochemical performance of the cell.The initial specific discharge capacity of the cell was 1 258.4 mAh/g at the current density of 0.1 mA/cm2,the discharge voltage platform stabilized around 2.7 V and charge voltage platform was 4.2 V.
Keywords:nano-nickel oxide(NiO)  catalyst  lithium peroxide(Li2O2)  Li-oxygen cell  
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