塔里木盆地煤岩显微组分热模拟实验中液态烃特征研究

对塔里木盆地满加尔凹陷侏罗系演化程度较低(Ro=0.40%)的煤岩显微组分进行了从250℃到550℃(50℃为一温阶,恒温72h)的热模拟实验。用氯仿抽提获得了赋存在固体残余物中的可溶液态有机物,即饱和烃、芳烃和非烃。实验结果表明:1组成煤岩的显微组分产液态物时具有镜质组较早(主要发生在350℃时)、壳质组略晚(发生在400℃)且显微组分产率大小顺序为壳质组(1)>壳质组(2)>镜质组的特征;2各显微组分的液态烃产率均表现为壳质组>镜质组的特征,镜质组和壳质组均存在一个明显的产液态烃高峰,壳质组是煤岩中液态物质的主力贡献者,其产液态物率是镜质组的5～15倍;3在显微组分中,低演化阶段具低总烃、高非烃+沥青质的特征,随着煤化作用的加强,总烃有大于非烃+沥青质趋势。同时,在液态物产率高峰,饱和烃一般都占优势,不同显微组分液态物质的产程有所不同,因此,尽管在煤岩中壳质组是液态烃的主要来源,但由于其在煤岩中所占比较较小,难以肯定其为主力源,而尽管镜质组产液态物率低于壳质组,但因其是煤岩的主体部分,且具有广泛的分布,因此,应该是重视的对象;4不同显微组分的烷/芳值大于1,且壳质组的烷/芳值具有两阶段性。

CHARACTERISTICS OF LIQUID HYDROCARBON FOR TARIM COAL AND ITS MACERALS IN THERMAL PYROLYSIS EXPERIMENTS

The macerals of the low-mature coal (R_o=0.40%, from Manjia’er Depression, Tarim Basin, China) were subjected to closed system pyrolysis, in sealed gold tubes, under isothermal temperature conditions, ranging from 250 to 550℃ at temperature intervals of 50℃ (72 hours/sample). The soluble organic matters from pyrolysis residues and original coal sample were obtained by chloroform extraction, including saturated, aromatic and non-hydrocarbon fractions. The results show that the liquid substance generation fr...