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Synthesis of (Na2O,PbO)-Nb2O5, (Na2O,BaO)-Nb2O5, and (K2O,SrO)-Nb2O5 thin films using sol-gel method
Authors:Fei Peng  Dongsheng Li
Affiliation:
  • a School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive NW, Atlanta, GA 30332-0245, USA
  • b Fundamental and Computational Sciences Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA 99352, USA
  • Abstract:Homogeneous pore-free Ba2NaNb5O15, KSr2Nb5O15, and 2·Na2O-PbO-6·Nb2O5 thin films were fabricated on sapphire substrates using the sol-gel technique. By controlling the gelation and coating process, thickness of thin films fabricated was controllable from ~ 40 nm to ~ 10 μm. Synthesized thin films possessed highly preferred orientated microstructure. Another advantage of this method is the subsequent heat treatment temperature dramatically decreased compared with other methods. This increases stoichiometry control and makes the large scale fabrication more feasible and efficient.
    Keywords:Sol-gel   Ferroelectric properties   X-ray diffraction   Scanning electron microscopy
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