| 化合物i-PrOCS_2HgPh的合成、晶体结构及表征 |
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| 引用本文： | 马怀波. 化合物i-PrOCS_2HgPh的合成、晶体结构及表征[J]. 青岛科技大学学报(自然科学版), 2005, 26(1): 18-22 |
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| 作者姓名： | 马怀波 |
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| 作者单位： | 马怀波（青岛科技大学,配位化学研究所,山东,青岛,266042） |
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| 摘 要： | 标题化合物i PrOCS2HgPh属单斜晶系,空间群为P21 /c,晶胞参数a=1. 462 0(3)nm,b=2 144. 3(4)nm,c=1. 373 1 (3)nm,β=115 .06 (3)°,Z=4。化合物i PrOCS2HgPh呈线性结构,汞原子分别与S、C原子相联,形成有S—Hg—C键的化合物,且S—Hg—C呈线性。标题化合物分两步热分解, 400 6℃后标题化合物分解完全。
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| 关 键 词： | 金属有机化合物 iPrOCS2HgPh 晶体结构 线性 热性能 |
| 文章编号： | 1672-6987(2005)01-0018-04 |
| 修稿时间： | 2004-09-07 |
Synthesis and Crystal Structure Characterization of Organometallic Compound I-PrOCS2 HgPh |
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| MA Huai-bo. Synthesis and Crystal Structure Characterization of Organometallic Compound I-PrOCS2 HgPh[J]. Journal of Qingdao University of Science and Technology:Natutral Science Edition, 2005, 26(1): 18-22 |
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| Authors: | MA Huai-bo |
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| Abstract: | A novel crystal structure of the organometallic compound i-PrOCS_ 2HgPh was obtained, which belongs to monoclinic system,space group P2_1/c,with lattice parameters a=1.462 0(3)nm, b=2.144 3(4) nm,c=1.373 1(3)nm,β=115.06(3)°, Z=4. The crystal structure of i-PrOCS_ 2HgPh is linear and the atom of mercury is connected with atoms of sulphur and carbon. There were two steps of decomposition in the thermal analysis curve and the title compound decomposed completely after 400.6 ℃. |
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| Keywords: | organometallic compound i-PrOCS_ 2HgPh crystal structure linear structure thermal property |
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