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金属有机框架在超级电容器中的应用
引用本文:廖晨敏,何雨婷,赵家昌,唐博合金,唐敖民,孙艳红,徐菁利. 金属有机框架在超级电容器中的应用[J]. 上海工程技术大学学报, 2012, 26(1): 32-35. DOI: 10.3969/j.issn.1009-444X.2012.01.008
作者姓名:廖晨敏  何雨婷  赵家昌  唐博合金  唐敖民  孙艳红  徐菁利
作者单位:上海工程技术大学化学化工学院,上海,201620
基金项目:上海市科委纳米科技专项基金
摘    要:成功制备了金属有机框架M3(BTC)2·12H2O(M=Ni和Co),并将其应用于超级电容器电极材料中,通过X线衍射(XRD)表征发现,这些化合物具有同类型的结构,在6 mol/L电解液中,采用循环伏安法和1 000次充放电循环测试其电化学性能.实验表明:Ni3 (BTC)2·12H2O电极材料在扫描速率5 mV/s下,比电容达到了430 F/g;在高扫描速率200 mV/s下,比电容为154 F/g;在扫描速率5 mV/s下1 000次充放电测试其循环寿命后发现,比电容保持率为86%.

关 键 词:超级电容器   金属有机框架   比电容

Application of Metal-Organic Frameworks (MOFs) in Supercapacitors
LIAO Chen-min , HE Yu-ting , ZHAO Jia-chang , TANG Bo-he-jin , TANG Ao-min , SUN Yan-hong , XU Jing-li. Application of Metal-Organic Frameworks (MOFs) in Supercapacitors[J]. Journal of Shanghai University of Engineering Science, 2012, 26(1): 32-35. DOI: 10.3969/j.issn.1009-444X.2012.01.008
Authors:LIAO Chen-min    HE Yu-ting    ZHAO Jia-chang    TANG Bo-he-jin    TANG Ao-min    SUN Yan-hong    XU Jing-li
Affiliation:(College of Chemistry and Chemical Engineering,Shanghai University of Engineering Science,Shanghai 201620,China)
Abstract:Metal-Organic Frameworks(MOFs) M3(BTC)2·12H2O(M represents Ni and/or Co) were successfully synthesized and used as electrode materials for supercapacitors.These compounds revealed isostructural characterization by XRD patterns.Electrochemical properties were tested by cyclic voltammetry(CV) and 1 000 charging-discharging cycles in 6 mol/L electrolyte.The experimental result shows that Ni3(BTC)2·12H2O electrode exhibits a high specific capacitance of 430 F/g at scan rate of 5 mV/s and a low specific capacitance of 154 F/g when the scan rate was increased to 200 mV/s,86% of the specific capacitance could be maintained after 1 000 cycles at a 5 mV/s scan rate.
Keywords:supercapacitor  MOFs(Metal-Organic Frameworks)  specific capacitance
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