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复合助烧剂对0.4CaTiO3-0.6(Li1/2Nd1/2)TiO3陶瓷的低温烧结及性能的影响
引用本文:王应,黄金亮,杨留栓,顾永军,李谦.复合助烧剂对0.4CaTiO3-0.6(Li1/2Nd1/2)TiO3陶瓷的低温烧结及性能的影响[J].电子元件与材料,2011,30(4):6-9.
作者姓名:王应  黄金亮  杨留栓  顾永军  李谦
作者单位:河南科技大学材料科学与工程学院;
基金项目:河南省杰出青年基金资助项目(No.074100510008); 河南省教育厅自然科学研究计划资助项目(No.2009A430005); 河南省科技发展计划资助项目(No.092300410135)
摘    要:采用传统的固相反应法制备了0.4CaTiO3.0.6(Li1/2Nd1/2)TiO3(CLNT)微波介质陶瓷,研究了复合添加BaCu(B2O5)(BCB)和2ZnO-B2O3(ZB)玻璃对CLNT陶瓷的烧结特性、相组成、微观形貌及介电性能的影响.结果表明:复合添加质量分数3%的ZB玻璃和5%的BCB能使CLNT陶瓷的烧...

关 键 词:微波介质陶瓷  低温烧结  介电性能  BaCu(B2O5)  2ZnO-B2O3

Effects of composite sintering additive on low temperature sintering and dielectric properties of 0.4CaTiO_3-0.6(Li_(1/2)Nd_(1/2))TiO_3 ceramics
WANG Ying,HUANG Jinliang,YANG Liushuan,GU Yongjun,LI Qian.Effects of composite sintering additive on low temperature sintering and dielectric properties of 0.4CaTiO_3-0.6(Li_(1/2)Nd_(1/2))TiO_3 ceramics[J].Electronic Components & Materials,2011,30(4):6-9.
Authors:WANG Ying  HUANG Jinliang  YANG Liushuan  GU Yongjun  LI Qian
Affiliation:WANG Ying,HUANG Jinliang,YANG Liushuan,GU Yongjun,LI Qian(School of Materials Science and Engineering,Henan University of Science and Technology,Luoyang 471003,Henan Province,China)
Abstract:0.4CaTiO3-0.6(Li1/2Nd1/2)TiO3(CLNT) microwave dielectric ceramics were prepared by conventional solid reaction method.The effects of BaCu(B2O5)(BCB) and 2ZnO-B2O3(ZB)glass composite sintering additive on sintering behavior,phase composition,micromorphology and dielectric properties of CLNT ceramics were investigated.The results show that the sintering temperature of CLNT ceramics is effectively lowered from 1 300 ℃ to 925 ℃ by adding 3%(mass fraction) ZB and 5%BCB.With the addition of BCB,the relative permittivity(εr) increase first and then decrease,the dielectric loss decrease and then reach saturation,and the temperature coefficient of resonant frequency decrease.The CLNT ceramics doped with 3% ZB glass and 5% BCB sintered at 925 ℃ for 2 h show the optimum dielectric properties: εr=83.2,tanδ= 0.013 and τf=35.7×10–6/℃,which meets the requirements of the high permittivity materials for multilayer microwave components.
Keywords:microwave dielectric ceramic  low temperature sintering  dielectric properties  BaCu(B2O5)  2ZnO-B2O3  
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