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O3/H2O2 Treatment of Methyl-terf-Butyl Ether in Contaminated Waters: Effect of Background COD on the O3-Dose
Authors:Ali Safarzadeh-Amiri
Affiliation:Hydroxyl Systems Inc. , 9800 McDonald Park Rd, Sidney, BC, Canada , V8L 5W5
Abstract:The destruction of methyl-tert-butyl ether (MTBE) in contaminated waters by O3/H202 process was studied and the influence background COD, alkalinity, and hydrogen peroxide and MTBE concentrations on process treatment efficiency and ozone dosage was investigated. The treatment efficiency was evaluated by an Efficiency Index, which is based on electrical energy requirement for ozone production. It was found that the treatment efficiency decreases linearly with increasing concentrations of MTBE at constant background COD and with background COD at constant MTBE concentration. A simplified kinetic scheme was presented to account for these observations.
Keywords:Ozone  MTBE Oxidation  Advanced Oxidation  Hydrogen Peroxide  Alkalinity  Groundwater  Efficiency Index
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