| Abstract: | Acoustic cavitation results in substantial enhancement in the rates of various chemical reactions but the existing knowledge about the application of reactors based on acoustic cavitation is limited to very small capacities (of the order of few millilitres). In the present work, an overview of the application of acoustic cavitation for the intensification of chemical reactions has been presented briefly, discussing the causes for the observed enhancement and highlighting some of the typical examples. A novel reactor has been developed operating at a capacity of 7 dm3 and tested with two reactions, ie liberation of iodine from aqueous potassium iodide and degradation of formic acid. The energy efficiency of the reactor has been calculated and compared with the conventional sonochemical reactors. The effect of frequency of irradiation on the percentage conversion of the reactants has been studied. Due to quite low conversions in the case of formic acid degradation, further intensification was attempted using aeration, addition of hydrogen peroxide, and the presence of solid particles (TiO2). Compared with conventional reactors the novel reactor gives excellent results and it can be said that the future of using acoustic cavitation for process intensification lies in the development of large‐scale multiple frequency multiple transducer reactors. Copyright © 2003 Society of Chemical Industry |
