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Synthesis of novel magnetic polymer microspheres with amphiphilic structure
Authors:Xue‐Yong Liu  Xiao‐Bin Ding  Zhao‐Hui Zheng  Yu‐Xing Peng  Xin‐Ping Long  Xiao‐Chuan Wang  Albert S. C. Chan  C. W. Yip
Abstract:Novel magnetic polymer microspheres with amphiphilic structure ranging in diameter from 5 to 80 μm were prepared by dispersion copolymerization of styrene and poly(ethylene oxide) acrylamide macromonomer (MPEO) in the presence of Fe3O4 magnetic fluid. The effects of various polymerization parameters on the average particle size were systematically investigated. The average particle size was found to increase with increasing initiator concentration. It also increased with decreasing stabilizer concentration and MPEO concentration. The content of the amino groups localized in the microspheres ranged from 0.01 to 0.25 mmol/g. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1879–1884, 2003
Keywords:amphiphilic  magnetic  microsphere
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