Cyclic voltammetry of monel 400 in lithium hydroxide solution at elevated temperatures

The electrochemistry of Monel 400 in 1 mole/kg^?1 LiOH solution at 25, 125 and 250°C has been investigated using the technique of cyclic voltammetry. The general electrochemical behaviour is found to most closely approximate to that of the major component, nickel, although expansion of the current scale reveals anodic and cathodic peaks which probably arise from redox processes involving copper. The general similarity to nickel can be rationalized in terms of either the d electron theory for cupronickel alloys or phase separation, the latter being favoured in the present study. At 25°C the majority of charge consumed on sweeping the potential in the positive direction is involved in the formation of an oxide film at potentials close to oxygen evolution. This process is no longer observed at 250°C, due to a sharp reduction in the oxygen evolution overpotential with temperature. The majority of charge consumed on cyclic sweeping at this temperature is attributed to active dissolution of the nickel component of the alloy to form HNiO^?₂ (or Ni(OH)^?₂ (or Ni(OH)^?₃) at potentials slightly positive to the hydrogen evolution region.