| 在人为非定态反应条件下正丁烷氧化制顺酐VPO催化剂的稳定性 |
| |
| 引用本文： | 陈标华,李成岳,乔聪震. 在人为非定态反应条件下正丁烷氧化制顺酐VPO催化剂的稳定性[J]. 石油化工, 1999, 28(7): 452-454 |
| |
| 作者姓名： | 陈标华 李成岳 乔聪震 |
| |
| 作者单位： | 1. 北京化工大学化学工程学院,北京,100029
2. 河南大学化学系,河南省开封,475000 |
| |
| 基金项目： | 国家自然科学基金,中国石油化工集团公司联合资助 |
| |
| 摘 要： | 对三种工业ＶＰＯ催化剂的稳定性评价以及ＸＲＤ、ＸＰＳ和ＦＴ－ＩＲ等表征结果表明，国产催化剂中活性物相（ＶＯ）２Ｐ２Ｏ７的含量最高，无论在定态或人为非定态操作条件下持续运行，其性能都相对稳定；引进固定床和流化床反应器所用的催化剂不宜用于固定床反应器的人为非定态操作
|
| 关 键 词： | 正丁烷 选择氧化 顺酐 人为非定态操作 催化剂稳定性 |
| 修稿时间： | 1998－06－11 |
Performance of VPO Catalysts for n-Butane Oxidation to Maleic Anhydride Operated under Forced Unsteady-State |
| |
| CHEN Biao-hua,LI Cheng-yue,QIAO Cong-zhen. Performance of VPO Catalysts for n-Butane Oxidation to Maleic Anhydride Operated under Forced Unsteady-State[J]. Petrochemical Technology, 1999, 28(7): 452-454 |
| |
| Authors: | CHEN Biao-hua LI Cheng-yue QIAO Cong-zhen |
| |
| Abstract: | The performance of the VPO catalysts for n -butane oxidation to maleic anhydride operated under forced unsteady-state was studied.The conversion and selectivity were measured for three kinds of industrial VPO catalysts which had been used for different periods of time under unsteady-state operation to evaluate the performance of the catalysts.The catalysts involved were characterized with XRD,FT-IR and XPS.Results show that the performance of the domestic catalyst is relatively stable under both steady-state and forced unsteady-state conditions.The stability of the other two kinds of catalysts used respectively in fixed-bed reactor and fluidized-bed reactor are inferior to that of the domestic one. |
| |
| Keywords: | nZ -butane selective oxidation maleic anhydride forced unsteady-state operation stability of catalysts |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
