Methoxylation of methyl oleate in the presence of dealuminated Y faujasites in their protonic form |
| |
Authors: | Clément Lansalot-Matras Paul Lozano Daniel Pioch Annie Finiels Claude Moreau Sylvain Claude |
| |
Affiliation: | (1) Laboratoire de Génie des Procédés et Elaboration des Bioproduits, Unité Mixte de Recherche (UMR)/Centre de Coopération Internationale en Recherche Agricole pour le Développement (CIRAD) T64, CIRAD/Amélioration des Méthodes pour l'Innovation Scientifique, TA 40/16, 34398 Montpellier Cedex 5, France;(2) Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)/Centre National de la Recherche Scientifique/Université Montpellier, 8, Rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France;(3) Organisation Interprofessionnelle des Graines et Fruits Oléagineux (ONIDOL), 75008 Paris, France |
| |
Abstract: | Methoxylation of methyl oleate into methyl methoxy stearate was carried out in a batch reactor at temperatures ranging from
150 to 190°C in the presence of dealuminated H-Y faujasites as catalysts. In the presence of an excess of methanol, the H-Y
faujasite with a Si/Al ratio of 15 was shown to achieve the title reaction with a yield of methyl methoxy stearate that does
not exceed 40% because of the parallel formation, at comparable rates, of methyl oleate isomers identified as methyl elaidate,
methyl trans-vaccenate, and methyl cis-vaccenate. Isomerization reactions were confirmed to occur rapidly in an independent manner. FFA are also present in small
amounts owing to the in situ dehydration of methanol and subsequent hydrolysis of the esters. Finally, starting from pure oleic acid leads to results
similar to those obtained with methyl oleate as the starting material. |
| |
Keywords: | Lubricants methyl oleate methoxylation zeolites |
本文献已被 SpringerLink 等数据库收录! |
|