| 3-氨基-4-酰胺肟基呋咱的晶体结构（英） |
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| 引用本文： | 王军,董海山,黄奕刚,李金山.3-氨基-4-酰胺肟基呋咱的晶体结构（英）[J].含能材料,2006,14(6):441-445. |
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| 作者姓名： | 王军 董海山 黄奕刚 李金山 |
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| 作者单位： | 中国工程物理研究院化工材料研究所,四川,绵阳,621900 |
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| 基金项目： | China Academy of Engineering Physics(No.2002Z0501) |
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| 摘 要： | 从水和乙醇的混合溶剂中培养出了3-氨基-4-酰胺肟基呋咱(AAOF)的单晶,用四圆单晶X-射线衍射仪、IR和元素分析对其结构进行了表征。结果表明, AAOF晶体属单斜晶系,空间群P21/C。晶体学参数为:Mr=143.12,a=0.7651(3) nm,b=1.1702(3) nm,c=1.9216(10) nm,β=96.47(4)°,V=1.7095(12) nm3,Z=4,Dc=1.668 g·cm-3,F(000) =888。AAOF分子平面性好,晶体中存在分子内和分子间氢键。
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| 关 键 词： | 物理化学 含能化合物 3-氨基-4-酰胺肟基呋咱(AAOF) 晶体结构 |
| 文章编号： | 1006-9941（2006）06-0441-05 |
| 收稿时间： | 2006-06-20 |
| 修稿时间： | 2006-08-29 |
Crystal Structure of 3-Amino-4-acylaminoximinofurazan |
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| WANG Jun,DONG Hai-shan,HUANG Yi-gang and LI Jin-shan.Crystal Structure of 3-Amino-4-acylaminoximinofurazan[J].Chinese Journal of Energetic Materials,2006,14(6):441-445. |
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| Authors: | WANG Jun DONG Hai-shan HUANG Yi-gang and LI Jin-shan |
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| Affiliation: | Institute of Chemical Materials, CAEP, Mianyang 621900, China;Institute of Chemical Materials, CAEP, Mianyang 621900, China;Institute of Chemical Materials, CAEP, Mianyang 621900, China;Institute of Chemical Materials, CAEP, Mianyang 621900, China |
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| Abstract: | The single crystal of 3-amino-4-acylaminoximinofurazan (AAOF) was cultured using the mixed solvent of water and ethanol. The structure was characterized by 4-circle single-crystal X-ray diffraction analysis,IR and elemental analysis. The results indicate that the crystal belongs to monoclinic,space group P21/C with the crystallographcial parameters of a=0.7651(3) nm,b=1.1702(3) nm,c=1.9216(10) nm,Mr= 143.12,β=96.47 (4)°,V=1.7095(12) nm3,Z=4,Dc=1.668g·cm-3,F(000)=888. The AAOF molecule is good planar. There are inter- and intramolecular hydrogen bonds in the crystal. |
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| Keywords: | physical chemistry energetic compound 3-amino-4-acylaminoximinofurazan (AAOF) crystal structure |
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