Institut für Physikalische Chemie der Universität Mainz, Jakob - Welder - Weg 15, 6500, Mainz, Germany
Abstract:
We describe a simple light scattering set-up for measuring interdiffusion coefficients D in polymer blends by generating spinodal decomposition and subsequent dissolution after temperature jumps across the phase boundary. In blends of polystyrene and polymethylstyrene (random copolymer of 60% m-methylstyrene and 40% p-methylstyrene) D values were obtained between 10?11 and 10?15 cm2s?1 at temperatures up to 50 K above the upper critical solution temperature. The results are discussed in relation to tracer diffusion in the same system.