| Standard Gibbs Energies of Transfer for KBPh4 from Water to Water ＋ PrOH and Water ＋ TBA Mixtures and the Primary Medium Effects |
| |
| 引用本文： | 邹立壮,王晓玲,朱书全.Standard Gibbs Energies of Transfer for KBPh4 from Water to Water ＋ PrOH and Water ＋ TBA Mixtures and the Primary Medium Effects[J].中国矿业大学学报(英文版),2002,12(2):126-132. |
| |
| 作者姓名： | 邹立壮 王晓玲 朱书全 |
| |
| 作者单位： | SchoolofChemicalandEnvironmentalEngineering,CUMT,Beijing100083,China |
| |
| 摘 要： | The standard Gibbs energiics of transfer (△rG^0) for potassium tetraphenylborate (KBPh4) have been studied in the system of water and water l-propamol (PrOH) as well as water and water t-butyl alcohol (TBA) at 298.15K. The rcsults show that -△rG^0 cxhibits a complicated changing pattern with the mole fraction of TBA(x (TBA)) or PrOH (x (PrOH)), and △rG^0 has the a maximum value at x (TBA) = 0.2 or x (PrOH) = 0.2. Especially, -△rG^0 of KBPh4 changcs unusually with increasing x (TBA) when x (TBA) ＜0.05. The reasons for these changes were analyzed and discussed.
|
| 关 键 词： | 四苯硼钾 标准迁移自由能 转移熵 水 氯化纳 氯化钾 |
Standard Gibbs Energies of Transfer for KBPh4 from Water to Water+PrOH and Water+TBA Mixtures and the Primary Medium Effects |
| |
| ZOU Li zhuang,WANG Xiao ling,ZHU Shu quan.Standard Gibbs Energies of Transfer for KBPh4 from Water to Water+PrOH and Water+TBA Mixtures and the Primary Medium Effects[J].Journal of China University of Mining and Technology,2002,12(2):126-132. |
| |
| Authors: | ZOU Li zhuang WANG Xiao ling ZHU Shu quan |
| |
| Abstract: | The standard Gibbs energies of transfer (ΔtrG0) for potassium tetraphenylborate (KBPh4) have been studied in the systems of water and water +1-propanol (PrOH) as well as water and water + t-b utyl alcohol (TBA) at 298.15*$K. The results show that -ΔtrG 0 exhibits a complicated changing pattern with the mole fraction of TBA(x (TBA)) or PrOH (x (PrOH)), and ΔtrG0 has the a m ax imum value at x (TBA) = 0.2 or x (PrOH)=0.2. Especially, -ΔtrG0 of KBPh4 changes unusually with increasing x (TBA) when x (TBA) < 0.05. The reasons for these changes were analyzed and discussed. |
| |
| Keywords: | potassium tetraphenylborate standard Gibbs energy of transfer activity coefficient medium effect $$$$ |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
