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无模板剂二次生长法合成MFI分子筛膜的生长机理
引用本文:蒋海洋,张宝泉,林跃生,李永丹. 无模板剂二次生长法合成MFI分子筛膜的生长机理[J]. 化工学报, 2005, 56(6): 1141-1143
作者姓名:蒋海洋  张宝泉  林跃生  李永丹
作者单位:天津大学化工学院催化科学与工程系,天津,300072;天津大学化工学院催化科学与工程系,天津,300072;Department of Chemical and Materials Engineering, Arizona State University, Tempe, AZ85287-6006,USA
基金项目:国家自然科学基金项目(50228203,20476076).~~
摘    要:Based on two template-free secondary growth methods, the formation mechanism of single-layer and multi-layer zeolite membranes was investigated. The composition of the synthesis solution did not affect the membrane structure, whereas the position-setting of the seeded support in the synthesis solution and the ageing process of the synthesis solution were two critical factors in the formation of the membrane. The synthesis solution with lower viscosity could easily penetrate into the gap between seeds boundaries, resulting in the formation of multi-layer membranes.

关 键 词:分子筛膜  无模板剂二次生长法  生长机理
文章编号:0438-1157(2005)06-1141-03
收稿时间:2004-12-01
修稿时间:2005-3-29 

Formation mechanism of MFI type zeolite membrane by template-free secondary growth
Jiang Haiyang,Zhang Baoquan,LIN Yaosheng,Li Yongdan. Formation mechanism of MFI type zeolite membrane by template-free secondary growth[J]. Journal of Chemical Industry and Engineering(China), 2005, 56(6): 1141-1143
Authors:Jiang Haiyang  Zhang Baoquan  LIN Yaosheng  Li Yongdan
Abstract:Based on two template-free secondary growth methods, the formation mechanism of single-layer and multi-layer zeolite membranes was investigated. The composition of the synthesis solution did not affect the membrane structure, whereas the position-setting of the seeded support in the synthesis solution and the ageing process of the synthesis solution were two critical factors in the formation of the membrane. The synthesis solution with lower viscosity could easily penetrate into the gap between seeds boundaries, resulting in the formation of multi-layer membranes.
Keywords:zeolite membrane  template-free secondary growth method  growth mechanism  
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