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Facile preparation and electrochemical characterization of graphene/ZnO nanocomposite for supercapacitor applications
Authors:Ananthakumar Ramadoss  Sang Jae Kim
Affiliation:1. Nanomaterials and System Lab, Faculty of Applied Energy System, Science and Engineering College, Jeju National University, Jeju 690-756, Republic of Korea;2. Nanomaterials and System Lab, Department of Mechatronics Engineering, Engineering College, Jeju National University, Jeju 690-756, Republic of Korea
Abstract:Graphene/ZnO nanocomposites were successfully synthesized by microwave-assisted method. The structure, morphology, optical and composition of the obtained samples were characterized using XRD, FT-IR, laser Raman, UV–Vis spectroscopy and XPS analysis. XRD analysis confirmed the presence of graphene/ZnO nanocomposite. FE-SEM image reveals that the homogenous distribution of ZnO nanoparticles on the graphene nanosheets. The electrochemical properties of the graphene/ZnO electrodes were analyzed by cyclic voltammetry and impedance spectroscopy. The results confirmed that the incorporation of ZnO nanoparticles enhanced the capacitive performance of graphene electrode. Graphene/ZnO nanocomposite electrode showed higher capacitance value of 109 F g−1 at a scan rate of 5 mV s−1 in 1 M KCl solution as compared to the graphene electrodes. These results demonstrated the importance and great potential of graphene based composites in the development of high-performance energy-storage systems.
Keywords:Composite materials   Nanostructures   Microstructure   Electrochemical properties
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