乙炔热裂解沉积对PAN基炭纤维性能的影响

利用有机溶剂去除PAN基炭纤维表面的集束剂与染剂.然后通过乙炔热裂解沉积对其进行表面改性,以期获得兼具高机械强度和优良导电性的高性能PAN基炭纤维.采用SEM、AFM、XRD、Raman等方法对PAN基炭纤维在改性前后的微观结构、结晶性、抗拉强度、弹性模量、导电性等进行了分析.研究结果表明采用化学气相沉积法可以提高或者明显改善石墨化处理后的PAN基炭纤维的力学性能(抗拉强度为2GPa,弹性模量为270GPa)和导电性(5×10-4Ω·cm).

The effect of a chemical vapor deposited carbon film from acetylene on the properties of graphitized PAN-based carbon fibers

Polyacrylonitrile (PAN)-based carbon fibers (CFs) were coated with a carbon film by chemical vapor deposition using acetylene as precursor. The morphologies of the as-received and modified CFs were observed using SEM and AFM, and their mechanical properties, crystalline parameters, and electrical conductivity were measured after graphitization. It was found that the graphitized CFs that were prepared showed excellent mechanical properties (2 GPa for strength and 270 GPa for modulus) and good electrical conductivity, (5 × 10 -4Ωcm) compared with the unmodified ones.