| 聚丁二烯型丙烯酸羟基酯的紫外光固化行为 |
| |
| 引用本文： | 李志春,黄家贤,陈汉佳,朱端慧,李玉廷,石金贞,冯志豪,安宁. 聚丁二烯型丙烯酸羟基酯的紫外光固化行为[J]. 高分子材料科学与工程, 1999, 15(5): 141-144 |
| |
| 作者姓名： | 李志春 黄家贤 陈汉佳 朱端慧 李玉廷 石金贞 冯志豪 安宁 |
| |
| 作者单位： | 1. 南开大学化学系,天津,300071
2. 燕山石油化公司合成橡胶厂,北京,102503 |
| |
| 摘 要： | 通过改变紫外光的光强，光致引发剂的种类和浓度，以及活性稀释剂三羟基甲丙烷三丙烯酸的浓度，研究了１００％和局部丙烯酸酯化的液体环聚丁二烯型丙烯酸羟基酯的有关光固化，热固化和光热联立固化行为，研究了酯化度不同的大分子丙烯酸羟基酯固化体系，在不同紫外光强下的热焓及双键转人率，并讨论了有关光致引发体系的诱导期和反应机制。
|
| 关 键 词： | 大分子丙烯酸羟基酯 紫外光强 差示扫描量热法 诱导期 |
| 修稿时间： | 1998－11－17 |
UV-LIGHT INITIATE CURING BEHAVIOR OF POLYBUTADIENE HYDROXYL ACRYLATE |
| |
| Li Chunrong,Huang Jiaxian,Chen Hanjia,Zhu Duanhui,Li Yuting,Shi Jinzhen,Feng Zhihao,An Ning. UV-LIGHT INITIATE CURING BEHAVIOR OF POLYBUTADIENE HYDROXYL ACRYLATE[J]. Polymer Materials Science & Engineering, 1999, 15(5): 141-144 |
| |
| Authors: | Li Chunrong Huang Jiaxian Chen Hanjia Zhu Duanhui Li Yuting Shi Jinzhen Feng Zhihao An Ning |
| |
| Abstract: | By changing the intensity of UV light, the species and concentration of photosensitive initiators and reactive diluent trihydroxymethyl propane triacrylate(THMPTA), the behaviors of light and heat curing as well as light heat combined curing of liquid polybutadiene hydroxyl acrylate by 100% or/and partially esterification of LEPB with acrylic acid are studied. The enthalpy and double bond conversiton ratio at different intensity of UV light in the curing system of macromolecule hydroxyl acrylate having different degree of esterification are also studied. Some related induction period and reaction mechanism in the system of light initiation have been discussed lastly. |
| |
| Keywords: | macromolecular hydroxy acrylate intensity of UV light DSC induction period |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
