| 丙烷脱氢催化反应机理及动力学研究进展 |
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| 引用本文： | 刘淑鹤,方向晨,张喜文,张海娟.丙烷脱氢催化反应机理及动力学研究进展[J].化工进展,2009,28(2):259. |
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| 作者姓名： | 刘淑鹤 方向晨 张喜文 张海娟 |
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| 作者单位： | 辽宁石油化工大学化学与材料科学学院；抚顺石油化工研究院 |
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| 摘 要： | 从化学反应原理、热力学性质和催化剂等角度出发，概述了丙烷无氧脱氢和有氧脱氢的反应体系；详述了无氧脱氢催化剂体系中的Pt系、Cr系和ZSM-5分子筛催化剂、氧化脱氢催化剂体系中的钒基催化剂V-Mg-O，V2O5/ZrO2上的脱氢反应机理和动力学研究。
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| 关 键 词： | 丙烷 脱氢 催化反应机理 反应动力学 |
Advances in catalytic mechanisms and kinetics of propane dehydrogenation |
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| LIU Shuhe,FANG Xiangchen,ZHANG Xiwen,ZHANG Haijuan.Advances in catalytic mechanisms and kinetics of propane dehydrogenation[J].Chemical Industry and Engineering Progress,2009,28(2):259. |
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| Authors: | LIU Shuhe FANG Xiangchen ZHANG Xiwen ZHANG Haijuan |
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| Affiliation: | School of Chemistry & Material science，Liaoning University of Petroleum & Chemical Technology；Fushun Research Institute of Petroleum and Petrochemicals |
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| Abstract: | The non-oxidative and oxidative dehydrogenation of propane to propylene based on the principles of chemical reaction,thermodynamics,catalysts is summarized.The mechanisms and kinetics of dehydrogenation reaction over Pt,Cr or ZSM-5 zeolite catalysts,and oxidative dehydrogenation over V-Mg-O and V2O5/ZrO2 catalysts are discussed in detail. |
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| Keywords: | propane dehydrogenation catalytic mechanism reaction kinetics |
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