Abstract: | Gas-liquid equilibrium conditions in binary mixtures of hydrogen and thianaphthene were experimentally determined at temperatures of 190 to 430°C and pressures to 250 atm in a flow apparatus. The same apparatus was also employed to measure the vapor pressure of thianaphthene. Comparisons of the new mixture data with Chao-Seader and Grayson-Streed correlations show that both correlations predict the thianaphthene equilibrium ratios well but are in error by up to about 45 and 35% respectively for K-values of hydrogen. |