| 糠醛常压气相催化加氢制糠醇 |
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| 引用本文： | 周亚明,沈伟,徐华龙,胡蕙,项一非.糠醛常压气相催化加氢制糠醇[J].石油化工,1997(1). |
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| 作者姓名： | 周亚明 沈伟 徐华龙 胡蕙 项一非 |
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| 作者单位： | 复旦大学化学系 |
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| 摘 要： | 利用固定床连续反应装置，研究了铜系催化剂对糠醛在常压下加氢制糠醇的催化性能。通过对众多的催化剂的筛选，得到了一种无毒、高效的加氢催化剂ＦＤＫ－１，考察了反应条件对催化性能的影响。ＸＲＤ测试表明，活性与ＣｕＯ有关，ＡＥＳ测试表明Ｃｕ－Ｚｎ－Ｏ（“□”是氧空位）构成糠醛加氢反应的活性中心。
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| 关 键 词： | 糠醛 加氢 糠醇 铜锌催化剂 |
Furfuryl Alcohol from Furfural by Hydrogenation under Atmospheric Pressure |
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| Zhou Yaming,Shen Wei,Xu Hualong,Hu Hui and Xiang Yifei.Furfuryl Alcohol from Furfural by Hydrogenation under Atmospheric Pressure[J].Petrochemical Technology,1997(1). |
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| Authors: | Zhou Yaming Shen Wei Xu Hualong Hu Hui and Xiang Yifei |
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| Abstract: | A series of Cu catalysts for hydrogenation of furfural to furfuryl alcohol under normal pressure have been studied in a fixed bed flow reactor A non toxic and highly selective catalyst FDK 1 has been found The effects of reaction conditions on the catalytic activity are examined and a yield of furfuryl alcohol as high as 98% is obtained Results of XRD and AES show that the catalytic activity depends on Cu 0 and the structure of the active unit is Cu Zn □ O is oxygen vacancy) |
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| Keywords: | furfuryl alcohol furfural catalysts Cu Zn hydrogenation |
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