改性环氧PBA/PMMA核壳乳胶粒子的制备与应用 |
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引用本文: | 马立群,李艳东,王雅珍,刘洪成,汪建新.改性环氧PBA/PMMA核壳乳胶粒子的制备与应用[J].齐齐哈尔轻工业学院学报,2012(3):1-3. |
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作者姓名: | 马立群 李艳东 王雅珍 刘洪成 汪建新 |
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作者单位: | [1]齐齐哈尔大学,黑龙江齐齐哈尔161006 [2]齐齐哈尔大学材料科学与工程学院,黑龙江齐齐哈尔161006 |
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基金项目: | 国家自然科学基金(U1162123,51103076);黑龙江省自然科学基金(ZD201101);黑龙江省自然基金(重点)(ZD201009) |
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摘 要: | 采用半连续种子乳液聚合工艺制备核壳结构的聚丙烯酸丁酯,(聚甲基丙烯酸甲酯-衣康酸-双酚A环氧树脂)(PBA/P(MMA—ITA—DGEBA))乳胶粒子。并通过红外光谱仪(IR)对乳胶粒子进行了表征,证明乳胶粒子具有壮粒子结构。将壳层带有环氧基的核壳乳胶粒子对环氧树脂进行增韧,通过扫描电子显微镜(SEM)对固化物冲击断面进行观测,改性核壳乳胶粒子对环氧树脂起到明显增韧效果,并提升了与环氧树脂的相容性。
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关 键 词: | 改性 核壳 乳胶粒子 环氧树脂 |
Preparation and application of PBA/PMMA core-shell atex particles modified with epoxy resin |
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Affiliation: | MA Li-qun, LI Dong-yan, WANG Ya-zhen, LIU Hong-cheng, WANG Jlan-xin ( 1. Qiqihar University, Heilongjiang Qiqihar 161006, China ; 2. College of Materials Science and Engineering, Qiqihar University, Heilongjiang Qiqihar 161006, China ) |
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Abstract: | The PBA/P (MMA-ITA-DGEBA) latex particles were prepared by semi-continuous seed emulsion polymerization process. FI-IR was used to characterize latex with core-shell structure. Epoxy resin was toughened by latex particles with an epoxy-based core-shell. Cross section of cured resin was observed by SEM micrograph. A significant effect was significant effect in toughening of modified core-shell latex particles. Compatibility between modified core-shell latex and epoxy resin were improved. |
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Keywords: | modification core-shell latex particles epoxy resin |
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