| 丁炔二羧酸金属配合物的合成与结构化学研究 |
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| 引用本文： | 徐畅,杨海萍. 丁炔二羧酸金属配合物的合成与结构化学研究[J]. 齐齐哈尔轻工业学院学报, 2012, 0(4): 21-23 |
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| 作者姓名： | 徐畅 杨海萍 |
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| 作者单位： | 齐齐哈尔市排水处城市排水监测站,黑龙江齐齐哈尔161000 |
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| 摘 要： | 以丁炔二羧酸为配体与金属盐反应，得到金属配合物，并对其结构进行了表征。在配合物C20H18ErN2O9中，晶体属单斜晶系，空间群为P21／co a=0．9711（19）nm，b=0．9866（2）nm，c=2．2684（5）nm，肛94．55（3）。铒原子为八配位反四棱柱构型，并以丁炔二羧酸桥联构成了一维梯子链，且通过氢键作用形成了三维超分子网络结构。
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| 关 键 词： | 配合物 丁炔二羧酸 合成 晶体结构 |
Synthesis and structure chemical research on acetylenedicarboxylate acid metal complex |
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| XU Chang,YANG Hai-ping. Synthesis and structure chemical research on acetylenedicarboxylate acid metal complex[J]. , 2012, 0(4): 21-23 |
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| Authors: | XU Chang YANG Hai-ping |
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| Affiliation: | ( Qiqihar Drainage Monitoring Station of City Water Quality, HeilongjiangQiqiharl61000, China) |
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| Abstract: | In this paper, a new metal complex has been prepared by the reaction of metal salt with acetylenedicarboxylate acid, The crystal structure and property of the complex was characterized. In the complex C20H18ErN2O9 （I）, the Er atom is eight-coordinate anti-quadrangular coordination geometry, forming one dimensional ladder-like structure. Hydrogen bond interaction exists in the structure, forming three-dimensional supramoleeular network. |
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| Keywords: | complex acetylenedicarboxylate acid synthesis crystal structure |
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