Heterogeneous Enzyme Mimics Based on Zeolites and Layered Hydroxides |
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Authors: | Dirk E. De Vos Bert F. Sels Pierre A. Jacobs |
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Affiliation: | (1) Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, 3001 Leuven, Belgium |
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Abstract: | Careful combination of a metal compound,a ligand and an inorganic support material leads to supramolecular catalysts that mimic the structural, organizational and functional aspects of enzyme activity.After discussing essential features of metalloenzyme-catalyzed reactions and coordination chemistry in inorganic hosts, we present examples of supramolecular materials selected from our own work that eventually resulted in useful catalysts for organic transformations in the liquid phase. |
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Keywords: | biomimetic catalysis zeolites layered double hydroxides organic catalysis |
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