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| 2,5-二[(2-羟乙基)氨基]-1,4-苯醌合成的新方法 | |
| 引用本文： | 王建,刘玮炜,马卫兴,尹福军,许兴友,陆路德. 2,5-二[(2-羟乙基)氨基]-1,4-苯醌合成的新方法[J]. 精细石油化工, 2010, 27(2) |
| 作者姓名： | 王建 刘玮炜 马卫兴 尹福军 许兴友 陆路德 |
| 作者单位： | 1. 淮海工学院,江苏,连云港,222005 2. 淮海工学院,江苏,连云港,222005;南京理工大学,江苏,南京,210094 3. 南京理工大学,江苏,南京,210094;淮阴工学院,江苏,淮安,223003 4. 南京理工大学,江苏,南京,210094 |
| 基金项目： | 江苏省教育厅自然科学基金资助项目，江苏省"六大人才高峰"项目，连云港市科技攻关计划项目，淮海工学院博士科研启动项目，自然科学课题 |
| 摘 要： | 实验以姜黄素和乙醇胺为原料,于45℃回流2 h,得到紫红色产物2,5-二[(2-羟乙基)氨基]-1,4-苯醌,产率约2.6%。经单晶培养和IR、NMR、MS及单晶X衍射等方法对产物进行了确证,并对该新反应机理进行了初步分析。 |
| 关 键 词： | 2,5-二[(2-羟乙基)氨基]-1,4-苯醌 姜黄素 乙醇胺 合成 结构 机理 |
A NEW METHOD FOR SYNTHESIS OF 2,5-BIS[(2-HYDROXYETHYL)AMINO]BENZO-1,4-QUINONE |
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| Wang Jian,Liu Weiwei,Ma Weixing,Yin Fujun,Xu Xingyou,Lu Lude. A NEW METHOD FOR SYNTHESIS OF 2,5-BIS[(2-HYDROXYETHYL)AMINO]BENZO-1,4-QUINONE[J]. Speciality Petrochemicals, 2010, 27(2) | |
| Authors: | Wang Jian Liu Weiwei Ma Weixing Yin Fujun Xu Xingyou Lu Lude |
| Affiliation: | Wang Jian~1,Liu Weiwei~1,Ma Weixing~1,Yin Fujun~(1,2),Xu Xingyou~(2,3) and Lu Lude~2 (1.Huaihai Institute of Technology,Lianyungang 222005,Jiangsu,China,2.Nanjing University of Science and Technology,Nanjing 210094,3.Huaiyin Institute of Technology,Huaian 223003,China) |
| Abstract: | 2,5-Bis[(2-hydroxyethyl) amino] benzo-1,4-quinone was synthesized with Curcumin and ethanolamine as the raw materials to reflux under the temperature of 45℃ for 2 h.The product was purplish red and characterized by IR,NMR,MS and single crystal X-ray diffraction.The mechanism of this novel reaction was initially investigated,which laid a foundation for further improvement to the synthesis method. |
| Keywords: | 2 5-bis[(2-hydroxyethyl)amino]benzo-1 4-quinone curcumin ethanolamine synthesis structure mechanism |
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